神府煤中低温热解前后表面官能团和孔隙变化规律的研究

doi:10.11799/ce201512035

煤炭工程 ›› 2015, Vol. 47 ›› Issue (12): 114-117.doi: 10.11799/ce201512035

神府煤中低温热解前后表面官能团和孔隙变化规律的研究

赵世永¹,吴沛沛¹,徐婕²,李鑫³,张生军³,龙江⁴

1. 西安科技大学
2. 陕西煤业化工技术研究院有限公司
3. 陕西煤业化工技术研究院有限责任公司
4. 国土资源部煤炭资源勘查与综合利用重点实验室

收稿日期:2015-07-28 修回日期:2015-09-22 出版日期:2015-12-11 发布日期:2015-12-29
通讯作者: 赵世永 E-mail:zhaoshiyong9@163.com

Study?on?variation?of?facial?functional?groups?and?pore?before?and?after?the middle and low?temperature?pyrolysis?of?Shenfu?coal

Received:2015-07-28 Revised:2015-09-22 Online:2015-12-11 Published:2015-12-29

摘要/Abstract

摘要： 为研究神府煤热解前后表面官能团及孔隙的变化规律，选取神木红柳林煤矿原煤及以其为原料通过立式炉热解生产的半焦为研究对象，采用氮气吸附、扫描电镜、红外光谱及X光电子能谱等分析手段，对原煤及半焦样品进行了分析。实验结果表明，与原煤相比，半焦比表面积变大，拥有更发达的孔隙结构；半焦与原煤官能团相似，但含量不同；煤热解后，表面官能团发生变化，半焦表面C-C、C-O键增加，C-H、C=O和O=C-O键减少。

关键词: 神府煤, 半焦, 官能团, 孔结构, 比表面积, XPS

Abstract: Shenfu raw coal and vertical furnace semi-coke were used to be investigated.Using Nitrogen adsorption, XPS, FTIR spectrum and SEM to analyses the raw coal and semi-cokes, which showed that the specific surface area was larger and the pore structures were more developed of semi-cokes,compared with raw coal.Functional groups of semi-cokes and raw coal are similar while the contents are different.Facial functional groups have been changed after coal pyrolysis, semi-cokes facial C—C、C—O bonds were increased, C—H、C=O and O=CO bonds were reduced.

Key words: Shenfu raw coal, semi-cokes, functional?groups, pore structure, XPS

中图分类号:

TQ531

赵世永，吴沛沛，李鑫，等. 神府煤中低温热解前后表面官能团和孔隙变化规律的研究[J]. 煤炭工程, 2015, 47(12): 114-117.

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参考文献

[1] 任庚坡，张超群，姜秀民，于立军。大同煤的表面微观结构分析[J].燃料科学与技术.2007,13(3):265-268.
Ren Geng-bo, Zhang Chao-qun, Jiang Xiu-min,etc. Analysis of Surface Area and Pore Structure of Datong Coal[J].Journal of Combustion Science and Technology. 2007,13(3):265-268.
[2]向银花,王洋,张建民，等. 煤焦气化过程中比表面积和孔容积变化规律及其影响因素研究[J].燃料化学学报.2002,30(2):108-112.
Xiang Yin-hua, Wang Yang, Zhang Jian-min,etc. Study on Structures and Their Affecting Factors During Gasification of Chars[J].Journal of Fuel Chemistry and Technology.2002,30(2):108-112.
[3]沈伯雄，姚强，刘德昌，等.石油焦燃烧过程中比表面积和孔容积变化规律的实验研究[J].化工学报,2000,51(6):784-787.
Shen Bo-xiong, Yao Qiang, Liu De-chang, etc.Changes of Specific Pore Surface Area and Pore Volume of Petroleum Coke During Combustion[J].Journal of Chemical Industry and Engineering(China),2000,51(6):784-787.
[4] 段钰锋,周毅,陈晓平等。煤气化半焦的孔隙结构[J].东南大学学报.2005,35(1):135-139.
Duan Yu-feng, Zhou Yi, Chen Xiao-ping,etc. Pore structure of gasified coal-char[J].Journal of Southeast University.2005,35(1):135-139.
[5]王晓亮，李少华，赵庆。褐煤快速热解比表面积及孔隙结构变化规律[J].煤炭转化，2013，36（4）：6-9.
Wang Xiao-liang, Li Shao-hua, Zhao Qing. Specific Area and Pore Structure Evolution
During Lignite Fast Pyrolysis[J].Coal Conversion.2013，36（4）：6-9.
[6] 周毅。半焦孔隙结构和加压燃烧特性的试验研究[D].东南大学硕士学位论文，2005.
Zhou Yi. Experimental Study or Pore Structure and Combustion
Characteristic of Coal-chars at Elevated Pressure[D].?SouthEast University.2005.
[7] 李敏。煤表面含氧官能团的研究[D].太原理工大学硕士学位论文，2012。
Li Min. Research on Oxygen-containing Functional Groups on Coal Surface[D].Taiyuan University of Technology,2012.
[8] 朱学栋，朱子彬，韩崇家等。煤中含氧官能团的红外光谱定量分析[J].燃料化学学报.1999,27(4):335-339.
Zhu Xue-dong, Zhu Zi-bing, Hang Chong-jia,etc.Quantitative Determination of Oxygen-containing Functional Groups in Coal by FTIR Spectroscopy[J]. Journal of Fuel Chemistry and Technology. 1999, 27(4):335-339.
[9] Sing K S,Everett D H,Haul R A,et al. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity[J].Pure&Appl Chem,1985,57(4):603 619.
[10] 沈钟,赵振国,康万利. 胶体与表面化学[M]. 化学工业出版社.2012.
Shenzhong, Zhao zhen-guo, Kang wan-li. Colloid and surface chemistry[M].?Chemical?Industry?Press.
[11] 石金明,孙路石,向军,等. 兖州煤气化半焦表面官能团特征试验研究[J].中国电机工程学报,2010,30(5):17-22.
Experimental Study on Surface Functional Groups Characteristics of Yanzhou Semi-cokes of Gasification[J],Proceedings of the CSEE,2010,30(5):17-22.
[12] 吕淑湛.半焦末浮选脱灰试验及机理研究[D]. 西安科技大学硕士学位论文,2014.
Lv Shuzhan. Study on flotation deashing treatment experiment?and mechanism of semi-coke [D].Xi’an University of Science and Technology, 20144:9-11.
[13] 常海洲,王传格,曾凡贵,等.不同还原程度煤显微组分组表面结构XPS对比分析[J].燃料　化学学报.2006,34(4):389-394.
CHANG Hai-zhou,WANG Chuan-ge,ZENG Fan-gui etc. XPS comparative analysis of coal macerals with different reducibility[J]. Journal of Fuel Chemistry and Technology,2006,34(4):389-394.
[14] 向军,胡松,孙路石,等.煤燃烧过程中碳、氧官能团演化行为[J].化工学报.2006,57(9):2180-2184.
XIANG Jun,HU Song,SUN Lushi etc.Evolution of carbon and oxygen functional groups during coal combustion[J]. Journal of Chemical Industry and Engineering(China),2006,57(9):2180-2184.
[15] Liu Fen-rong, Li Wen, Guo Hui-qing, etc.XPS study on the change of carbon-containing groups and sulfur transformation coal surface[J].Journal of Fuel Chemistry and Technology.2011,39(2):81-84.

神府煤中低温热解前后表面官能团和孔隙变化规律的研究

Study?on?variation?of?facial?functional?groups?and?pore?before?and?after?the middle and low?temperature?pyrolysis?of?Shenfu?coal

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